The ReadMe product is very well polished and the support of Markdown means writing documentation is easy without a complicated editor layer to learn. There's also a palette of pre-configured widgets that you can drop into your pages to handle embedding code, images, custom HTML/CSS, tables, etc. if you want to get fancy.
Nearly every time I log in there's a new feature, bug fix or enhancement - it's great to see the guys build such a useful tool so quickly but without impacting quality or uptime.
* ReadMe powers http://dev.avisohq.com (warning: work-in-progress)